Physical aging and enthalpy relaxation of amorphous polyesters

Relaxed enthalpy and volume during physical aging: Their interrelation

Several papers have recently presented results of measurements of physical aging by studying the behavior of glassy materials quenched from temperatures above their glass transition temperature g T . The evolution of the aging process is usually followed by plotting the relaxed enthalpy versus the accompanying decrease in volume. Here, we focus on the slope of such plots, which are found to be ...

Glass transition and enthalpy relaxation of amorphous food saccharides: a review.

Many food materials exist in a disordered amorphous solid state due to processing. Therefore, understanding the concept of amorphous state, its important phase transition (i.e., glass transition), and the related phenomena (e.g., enthalpy relaxation) is important to food scientists. Food saccharides, including mono-, di-, oligo-, and polysaccharides, are among the most important major component...

determination of some physical and mechanical properties red bean

چکیده: در این تحقیق، برخی خواص فیزیکی و مکانیکی لوبیا قرمز به-صورت تابعی از محتوی رطوبت بررسی شد. نتایج نشان داد که رطوبت بر خواص فیزیکی لوبیا قرمز شامل طول، عرض، ضخامت، قطر متوسط هندسی، قطر متوسط حسابی، سطح تصویر شده، حجم، چگالی توده، تخلخل، وزن هزار دانه و زاویه ی استقرار استاتیکی در سطح احتمال 1 درصد اثر معنی داری دارد. به طوری که با افزایش رطوبت از 54/7 به 12 درصد بر پایه خشک طول، عرض، ضخام...

Anomalous Enthalpy Relaxation in Vitreous Silica

It is a challenge to calorimetrically determine the glass transition temperature (Tg) of vitreous silica. Here, we demonstrate that this challenge mainly arises from the extremely high sensitivity of the Tg to the hydroxyl content, but also from decrease of the Tg with repeating the calorimetric scans. It is known that the liquid fragility (i.e., the speed of the viscous slow-down of a supercoo...

Thermodynamics of Enthalpy Relaxation and Hole Formation of Polymer Glasses